Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations.
نویسندگان
چکیده
Recent advances in chiral-phosphine-catalyzed asymmetric annulation reactions; including annulations of allenes, alkynes, Morita-Baylis-Hillman (MBH) carbonates, and ketenes; and their applications in the synthesis of bioactive molecules and natural products are reviewed.
منابع مشابه
Chiral phosphines in nucleophilic organocatalysis
This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita-Baylis-Hillman (MBH) acetates, carbonates, and ketenes with activated alkenes and imines, allylic substitutions of MBH acetates and carbonates, Michael additions, γ-umpolung additions, an...
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ورودعنوان ژورنال:
- Aldrichimica acta
دوره 49 1 شماره
صفحات -
تاریخ انتشار 2016